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Benzoyl chloride, CAS:98-88-4

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  Post Date: Jan 12,2019
  Expiry Date: Jan 12,2020
  Detailed Description: Cas No. :98-88-4 Benzoyl chloride Basic information
Product Name: Benzoyl chloride
Synonyms: alpha-chloro-benzaldehyd;Benzaldehyde, alpha-chloro-;-Chlorobenzaldehyde;chloruredebenzoyle;LABOTEST-BB LTBB000456;Benzenecarbonyl chloride;BENZOIC ACID CHLORIDE;BENZOYL CHLORIDE
CAS: 98-88-4
MF: C7H5ClO
MW: 140.57
EINECS: 202-710-8
Product Categories: Pharmaceutical Intermediates;Organics;Absolute Configuration Determination (Exciton Chirality CD Method);Amino Group Labeling Reagents for HPLC;Analytical Chemistry;Biochemistry;Enantiomer Excess & Absolute Configuration Determination;Exciton Chirality CD Method (for Hydroxyl Groups);HPLC Labeling Reagents;Hydroxyl Group Labeling Reagents for HPLC;Nucleosides, Nucleotides & Related Reagents;Protecting Agents for Hydroxyl and Amino Groups;Protecting Agents, Phosphorylating Agents & Condensing Agents;Reagents for Oligosaccharide Synthesis;UV Detection (HPLC Labeling Reagents);A-B, Puriss p.a. ACSOrganic Building Blocks;Acid HalidesDerivatization Reagents;Analytical Reagents for General Use;Carbonyl Compounds;Derivatization Reagents HPLC;Puriss p.a. ACS;UV-VIS;ACS GradeProtection and Derivatization;Others;Protecting and Derivatizing Reagents;Essential Chemicals;Reagent Plus;Routine Reagents;Acid Halides;Organic Building Blocks;organic chemical;API Intermediate;alkyl chloride
Mol File: 98-88-4.mol

Benzoyl chloride Chemical Properties
mp -1 °C
bp 198 °C(lit.)
density 1.211 g/mL at 25 °C(lit.)
vapor density 4.88 (vs air)
vapor pressure 1 mm Hg ( 32 °C)
refractive index n20/D 1.553(lit.)
Fp 156 °F
storage temp. Store at 0-5°C
Water Solubility reacts
FreezingPoint -1℃
Sensitive Moisture Sensitive
Merck 14,1112
Stability: Stable. Combustible. Incompatible with strong oxidizing agents, water, alcohols, strong bases. Reacts violently with DMSO and vigorously with alkalies.
CAS DataBase Reference 98-88-4(CAS DataBase Reference)
NIST Chemistry Reference Benzoyl chloride(98-88-4)
EPA Substance Registry System Benzoyl chloride(98-88-4)

Safety Information
Hazard Codes C
Risk Statements 34-43-20/21/22
Safety Statements 26-45-36/37/39
RIDADR UN 1736 8/PG 2
WGK Germany 1
RTECS DM6600000
Hazard Note Corrosive
HazardClass 8
PackingGroup II
HS Code 29310095
Hazardous Substances Data 98-88-4(Hazardous Substances Data)

MSDS Information
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Benzoyl chloride English
SigmaAldrich English
ACROS English
ALFA English

Benzoyl chloride Usage And Synthesis
Chemical Properties Colorless liquid
Usage Benzoyl Chloride is used in the manufacturing of dye intermediates.
General Description A colorless fuming liquid with a pungent odor. Flash point 162°F. Lachrymator, irritating to skin and eyes. Corrosive to metals and tissue. Density 10.2 lb / gal. Used in medicine and in the manufacture of other chemicals.
Reactivity Profile Benzoyl chloride reacts violently with protic solvents such as alcohols, with amines and amides (for example dimethylformamide [Bretherick 1979 p. 6] ) and with inorganic bases. Causes the violent decomposition of dimethyl sulfoxide [Chem. Eng. News 35(9): 87 1957]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Friedel-Crafts acylation of naphthalene using Benzoyl chloride, catalyzed by AlCl3, must be conducted above the melting point of the mixture, or the reaction may be violent [Clar, E. et al., Tetrahedron, 1974, 30, 3296].
Health Hazard INHALATION: may irritate eyes, nose and throat. INGESTION: causes acute discomfort. SKIN: causes irritation and burning.

Benzoyl chloride Preparation Products And Raw materials
Preparation Products 1-BENZOYLPIPERAZINE HYROCHLORIDE 97-->2-Amino-5-nitrobenzophenone-->3-oxo-3-phenyl-propanamide-->QUINOLINE-2-CARBONITRILE-->APLPHA-BROMO-M-BENZOYLOXYACETOPHENONE-->Nitrazepam-->4-Chloro-2-methylaniline-->tert-Butyl peroxybenzoate-->4-BROMOPHENYLTHIOUREA-->1,3-DIBENZOYLOXYBENZENE-->Histamine-->Fast Blue BB-->N,N-Dimethylbenzamide-->N,N-Dimethylpiperidin-4-amine-->1-(PHENYLSULFONYL)-1H-INDOLE-2-CARBALDEHYDE-->2-AMINO-1-PHENYLETHANOL-->2,5-DICHLOROBENZOYL CHLORIDE-->dibenzoyl disulphide -->dihydroxyethyl p-octadecyl phenylsulfonyl amino propyl ammoium propylsulfonate-->N,N'-DIBENZOYLHYDRAZINE-->N-Phenylbenzohydroxamic acid-->2-(N,N-DIETHYLAMINOCARBONYL)PHENYLBORONIC ACID-->Benzoylferrocene-->4-Chlorobenzophenone-->3,4-Dichlorobenzophenone-->Benzoyl cyanide-->PHENOXYACETIC ACID-->Phenyl benzoate-->Chrysin-->(3,4-Diaminophenyl)phenylmethanone-->3-Chlorobenzoyl chloride-->7-HYDROXY-3-METHYLFLAVONE-->2-Methyoxy-3-methyl-2-phenyl-4H-benzo-g-pyranone-->Oxybenzone-->(+)-Dibenzoyl-D-tartaric acid-->Proglumide-->1-NAPHTHYL PHENYL KETONE-->1-BENZOYLPIPERIDINE-->DIBENZOYL THIAMINE-->Sucrose benzoate
Raw materials Toluene-->Chlorine-->Phosphorus trichloride-->PHOSGENE-->Benzoic acid-->Benzotrichloride

  CAS Registry Number:

98-88-4
  Synonyms: ;Benzoyl chloride 99.5+ % for analysis;Benzoil chloride;4-Chlorocarbonylpolystyrene;alpha-chloro-benzaldehyd;O-Chloroformylbenzene;
  Molecular Formula: C7H5ClO
  Molecular Weight: 140.56
  Molecular Structure: 98-88-4 Benzoyl chloride
  Hazard Symbols:  C:Corrosive;
  Risk Codes: R34:;
  Safety Description: S26:;
S36/37/39:;
S45:;

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