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MOCA,polyurethane curing agent, chain extender

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  Post Date: Jan 14,2014
  Expiry Date: Jan 14,2015
  Detailed Description: Cas No. :101-14-4 Quantity: NegotiableMetric Tons
Payment Method: TT/LC
Chemical Name: 4,4'-methylene-bis-(ortho-chloroaniline) (MOCA)
CAS No.: 101-14-4

SPECIFICATIONS
Appearance Pale yellow granular pellet
Melting range 98 -- 102
Moisture % < 0.30

PHYSICAL PROPERTIES
Bulk density (24) / g/cm3 1.44
Liquid density (107) / g/ml 1.26
Amine value / mmol/g 7.4-7.6
Free Aniline % < 1.00
Color (Gardner) < 4
Acetone insoluble matter % <0.04
Water absorption tendency None
Storage stability Stable, decomposes above 200

SOLUBILITY
Very soluble in Acetone, DMF, DMSO, MEK and THF.
Soluble in Ethanol, Toluene and Benzene.
Insoluble in water.

APPLICATIONS
Curing agent for polyurethane elastomers and cast polyurethanes.
Curing agent for epoxy or epoxy urethane resin.

FORMULATIONS
MOCA-HR is usually used to cure prepolymers that are produced from TDI reacted with polyether or polyester polyol. The prepolymer normally contains NCO of 4.2 - 4.3 %. Pot life is usually 8 - 10 minutes.
MOCA-HR will show a significant reduction in properties if heated for long periods of time at temperatures in excess of 121.

TOXICITY
LD50 (Rats) 5000mg/kg.
OSHA PEL 0.02ppm (8-hour TWA), ACGIH TLV 0.01ppm.
MOCA has been classified as a carcinogen since 1973, based upon test results with laboratory animals. In 1992, ACGIH, after reviewing existing information, continued the classification of MBOCA as a "Suspect Human Carcinogen".

STORAGE
MOCA-HR should be stored in a dry location.

PACKAGING
Net 50-kg carton drum with polyethylene liner.

  CAS Registry Number:

101-14-4

  Synonyms: ;4,4-Methylenebis(4-chloroaniline);2,2-dichloro-4,4-methylenedianiline;4,4-Methylene-Bis(Ortho-Chloroaniline);Bis-(4-Amino-2,3-dichlorophenyl)-methane;4,4'-Methylen-bis-(2-chloranilin);4,4'-Methylenebis-(2-chlroaniline);METHYLENE-BIS-ORTHOCHLOROANILINE;MOCA;4,4'-Diamino-3,3'-dichlorodiphenylmethane;Sulfonating Agent MOCA;3,3'-Dichloro-4,4'-Diaminodiphenyl methane;4,4'-Methylene-bis(o-chloroaniline);4,4'-methanediylbis(2-chloroaniline);4,4'-methanediylbis(3-chloroaniline);3,3'-methanediylbis(2-chloroanilinato);4'4-methylene-bis-(2-chloroaniline);MOCA-WH;4,4'-Methylene bis(2-chloroaniline);4,4-methylene-bis-(2-chloroaniline);3,3'-Dichloro-4,4'-diaminodiphenylmethane;
  Molecular Formula: C13H12Cl2N2
  Molecular Weight: 267.1538
  Molecular Structure: 101-14-4 4,4'-methylene-bis(2-chloroaniline)
  Hazard Symbols:  T:Toxic;
 N:Dangerous for the environment;
  Risk Codes: R22:;
R45:;
R50-53:;
  Safety Description: S45:;
S53:;
S60:;
S61:;

  Company: Suzhou Xiangyuan Special Fine Chemical Co,. Ltd     [ China ]        
  Contact: Michael Wang
  Tel: 8651267536550
  Fax: 8651267545159
  Email: michaelwang@chinamboca.com
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